A set of .NET Framework managed libraries for developing graphical user interfaces.
Maui only supports windows and mobile, so switching only makes sense if a mobile app made sense. While WPF is newer than Winform, like WinForm it’s a stable library (not in active development). Microsoft does not have a good UI roadmap for windows, and even Maui uses dated technology.
unless you are considering a web application instead of a desktop, I’d say you only need to upgrade to net 10. One disadvantage of .net core over the mature .net 4.* is you need to update every two years to the current version.